I vaguely remember learning that the 1934 Dodge had a metallic paint, using the word "poly" in the color name. Looking at <Autocolorlibrary.com> , they do not even list Cadillac from 1933 or 1935, so I looked at 1934 Dodge and did see "poly" colors in the list, so it seems likely that Cadillac did have a poly color in 1933, maybe even earlier.
Going to later years, I recall Cadillac and Olds having at least one premium acrylic lacquer color in 1956, other colors being the old nitrocellulose lacquers. Each succeeding year Cadillac and Olds, possibly Buick and Pontiac, also added more acrylic lacquer colors until 1959 when all were painted with acrylic lacquer.
My 2015 Holden/Chevrolet is metallic black, the only black Holden offered on that car, and it always looks dusty to me.