Hello Lrod67,
I have a '67 Sedan DeVille. When I refurbished my brakes a few years ago, I don't recall I had any trouble removing the bolts holding the front wheel cylinders. If a socket does not fit, use a box-end wrench, and be certain the head of the bolt is clean, and that the wrench fits squarely on the head of the bolt. I do not recommend the use of air/electric impact wrenches in confined/awkward positions.
I do not remember the size of the head of the bolts, but if you have a set of combination wrenches, one will probably be the correct size. Oddly, the bolt diameter and thread pitch is not listed in the shop manual brake section, but if there are SAE grade markings on the bolt heads, you can Google the correct torque specification. To read about my brake adventures, click here, and scroll to reply #25.
http://forums.cadillaclasalleclub.org/index.php?topic=133691.20If you still encounter difficulty removing the bolts attaching the wheel cylinders, please post a photo, and several of the forum members might be able top provide some tips.
Respectfully submitted,
Christopher Winter